[1,1′-Bis(diphenylphosphino)ferrocene]carbonyl[dihydrobis(pyrazol-1-yl)borato]hydridoruthenium(II) acetone solvate
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چکیده
In the title compound, [FeRu(C(17)H(14)P)(2)(C(6)H(8)BN(4))H(CO)]·C(3)H(6)O, the Ru(II) ion is coordinated in a distorted octa-hedral environment involving a hydride ligand, a carbonyl ligand and two bidentate ligands. Of the two bidentate ligands, the bulky 1,1'-bis-(diphenyl-phosphino)ferrocene (dppf) ligand chelates with a larger bite angle of 101.90 (2)°, whereas the bite angle of the [H(2)Bpz(2)](-) ligand (pz = pyrazol-yl) is 85.67 (7)°. The latter ligand creates an RuN(4)B six-membered ring with a boat conformation, which puckers towards the site of the small hydride ligand. The hydride ligand is cis with respect to the carbonyl ligand and trans to one of the P atoms of the dppf ligand. In the crystal structure, there are weak inter-molecular C-H⋯O hydrogen bonds between complex mol-ecules and acetone solvent mol-ecules.
منابع مشابه
trans-Carbonyl[dihydrobis(1,2,4-triazol-1-yl-κN 2)borato]hydridobis(triphenylphosphine-κP)ruthenium(II) acetonitrile solvate
In the crystal structure of the title compound, [Ru(C(4)H(6)BN(6))H(C(18)H(15)P)(2)(CO)]·C(2)H(3)N, discrete mononuclear complexes are found in which the Ru atom is coordinated by two triphenyl-phosphine (PPh(3)) ligands, one dihydro-bis(1,2,4-triazol-1-yl)borate ligand, one carbonyl ligand and one hydride atom within slightly distorted octa-hedra. The two P atoms of the PPh(3) ligands are tran...
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